ZnAl类水滑石制备温度对吸附剩余污泥脱水液中磷酸根的影响(英文)

编号：FTJS02851

篇名：ZnAl类水滑石制备温度对吸附剩余污泥脱水液中磷酸根的影响(英文)

作者：程翔； 叶杰旭； 孙德智； 陈爱燕；

关键词：excess sludge liquor； layered double hydroxides； phosphate adsorption； synthesis temperature；

机构： College of Environmental Science&Engineering,Beijing Forestry University； School of Municipal&Enviro

摘要： A group of Zn-Al layered double hydroxides (LDHs) were synthesized at different temperatures from 25-90 °C in order to investigate the influence of synthesis temperature on characteristics of the LDHs and their phosphate adsorption behaviour. The results reveal that an increase in the synthesis temperature generally improves the specific surface area of the sample and the phosphate adsorption capacity. The significantly enhanced crystallin- ity of the Zn-Al-30, synthesized at 30 °C, leads to a remarkable decrease in the specific surface area and consequently a poor phosphate adsorption capacity. It is suggested that the surface adsorption plays an important role in the phosphate uptake by the Zn-Al LDHs. Zn-Al-70 presents a relatively higher crystallinity and a lower specific surface area, compared with Zn-Al-60 and Zn-Al-80, but the highest phosphate adsorption capacity, indicating that surface adsorption is only one of the pathways for phosphate removal. The phosphate adsorption by the Zn-Al follows a pseudo-second-order kinetic equation. The adsorption isotherms fit Langmuir models, and the maximum a dsorption capacities of the Zn-Al-25, Zn-Al-50 and Zn-Al-70 are estimated to be 17.82, 21.01 and 27.10 mg·g-1 adsorbent, respectively.